Study Of Performance of Liquid Metal Containing Different Contents of Ag Particular Additives for Thermal Interface Materials
In the present research, we have studied the influence of Ag additives on wettability, adhesion, oxidation, viscosity and modulus of liquid metal on two alloys – Liquid Metal 1 (“LM1”) (62.5Ga, 21.5In, 13Sn) and Liquid Metal 2 (“LM2”) (78.6Ga, 21.4In)– to develop new thermal interface materials for IC modules such as CPU and GPU in PC and game stations. In this study, liquid metals were first mixed with Ag powders of up to 1.5wt%, followed by treatment with 30wt% NaOH aqueous solution to remove the oxide in the liquid metal, to prepare liquid metal/Ag composites. Wettability and adhesion have been studied on bare Cu, and Ni/Au surface finish Cu. Contact angle of liquid metal with and without Ag powders was measured to evaluate wettability of liquid metal on bare Cu and Ni/Au Cu. Adhesion of the liquid metals with and without Ag additive on bare Cu and Ni/Au Cu were evaluated by temperature cycling test with a profile of -40oC to 125oC, dwell time of 20min at low and high temperature. Oxidation of the liquid metals on bare Cu and Ni/Au Cu substrate was monitored over time at ambient atmosphere and during temperature cycling test, followed by characterizing cross-section morphology with SEM. To investigate effect of Ag powders on viscosity, the viscosity was measured using a parallel plate viscometer. Thermal properties and performance of the prepared composite in this research will be evaluated by measurement of thermal resistance and conductivity, respectively.
Keyword: Liquid metal, 51E, 300E, wettability, oxidation, viscosity and modulus.