iNEMI General Purpose Flowers of Sulfur Corrosion Chamber
The iNEMI flowers of sulfur (FoS) corrosion chamber was developed to study creep corrosion on printed circuit board assemblies(PCBAs). The chamber, typically run at 50 or 60oC, has corrosive sulfur and chlorine gases along with relative humidity controlled in the 11 to 90% range. The sulfur gas is emitted from a bed of sulfur and the chlorine gas from household bleach containing 8.25% sodium hypochlorite. The chamber has been used to study creep corrosion. It has reproduced creep corrosion on PCBAs from manufacturing lots that suffered creep corrosion in the field; shown that creep corrosion is a function of relative humidity; shown that creep corrosion originates where the solder mask overlaps the copper metallization on printed circuit boards (PCBs); and shown that PCB storage time reduces creep corrosion propensity in service. In addition, preliminary investigations have shown the chamber to be useful in determining corrosion rates of copper and silver as a function of relative humidity and temperature and for conformal coating characterization. The paper will review the above examples of the successful use of the iNEMI FoS chamber in addition to the research currently underway to develop a qualification test for surface mount resistors at a more realistic temperature of 70oC. The current qualification test for these resistors is run at an unrealistically high temperature of 105oC which most probably causes the resistors to fail with a mechanism different from that in the field.