The deployment of non-Lead (Pb) surface finishes is well underway throughout the electronics industry. Printed circuit boards,which for many years had relied on Hot Air Solder Level (HASL) finishing,have been using new flatter,Pb-free solderable finishes. Market tracking surveys indicate that the use of HASL has dropped below 50% of all PCB’s. HASL alternative finishes include Organic Solderability Preservative (OSP,) Electroless Nickel Immersion Gold (ENIG,) Immersion Silver,and Immersion Tin. While there are significant differences among the HASL alternative coatings,they do have certain characteristics in common. All HASL alternatives are much flatter and thinner coatings than HASL.
PCB surface finishes need to perform several functions. Archived literature provides information on the solderability,contact functionality,solderjoint reliability,and high speed signal integrity effects of the surface finish options. The summary contained herein describes a fundamental criterion of all board finishes: the ability to protect copper for subsequent soldering and field use. The surface finish,and therefore the underlying copper,can be compromised by exposure to harsh environments such as air pollution,condensing moisture,ionic liquid solutions,and contact with corroding materials. Surface finishes are more or less degraded based on the sensitivity of the surface finish to environmental contaminants and the thickness of the protective coating. For example,tin/lead is not especially resistant to corrosion,but it does have the advantage that it is deposited to such a thickness that it withstands corrosion relatively well.
Corrosion of copper circuitry begins as thin tarnish of the surface finish. Circuit functionality will be compromised only if the chemical pollutants,and the means to convey the pollutant,are present long enough to corrode the copper. This paper reviews some specific causes of corrosion,methods used to measure the corrosion,functional aspects of tarnish and corrosion,and methods employed to prevent surface corrosion. Of special interest,this paper reviews the use of ultrathin layer of tarnish protection on new HASL alternatives such as immersion silver. More specifically,the topic of creeping corrosion will be discussed as an example of the extreme results of tarnish and copper migration.