For many years, metals have been used as thermal interface materials (TIMs), and until recently, the most common type of metal TIM were solder TIMs. Due to their high reliability and thermal conductivity, metal TIMs are excellent solutions for heat dissipation in electronic systems, especially for more challenging applications. Thermal conductivity and interfacial resistance are the most important properties of TIMs. With devices becoming smaller, consuming more power, and producing more heat, finding the right TIM becomes a highly critical step in any electronic systems application. Recently, liquid metal TIMs have gained popularity, especially for the thermal management of high-performance computing semiconductor applications such as central processing units (CPUs), graphics processing units (GPUs), and multi-chip modules (MCMs). Due to their fluid nature, liquid metal (LM) TIMs do not need to be compressed to maintain even contact, and they can accommodate imperfections in the neighboring components. The newest metal TIMs are made of liquid metal paste (LMP). LMPs are materials that still have gallium-based LMs as a key component, but they also have some additives that change their mechanical and/or thermal properties. The goal of those LMPs is to solve some of the issues that LMs have as a TIM.
The first part of this paper addressed pure metal LMPs, where all additives were metals. This second part will discuss new types of LMPs that combine gallium-based LMs with polymeric materials, such as polymer LM hybrids or polymeric liquid metal pastes (PLMPs). Polymer LM hybrids or PLMPs look like standard thermal pastes or thermal greases, but they have a high LM content. Just like the LMPs presented in the first part, PLMPs are less prone to oxidation and humidity, will have better performance in thermal cycling (-40/+125˚C) than LMs, and are electrically non-conductive* despite the high LM count used to create PLMPs. This paper addresses the challenges of the recommended dispensing process for the high-volume production of those PLMPs.
*PLMPs are electrically non-conductive at time zero (T0). More testing is required to prove that they will stay that way over time and that there will be no separation of LMs from PLMPs.
Key words: Bondline thickness (BLT), coefficient of variation (CV), dispensing, jetting, liquid metal (LM), liquid metal paste (LMP), polymeric liquid metal paste (PLMP), phase change material (PCM), solder paste inspection (SPI), thermal interface material (TIM), thermal test vehicle (TTV)
Author(s)
Sunny Agarwal, Miloš Lazić, Dr. Ricky McDonough, Ph.D.