Development and Enhancement of Low Temperature Soldering Solution for SMT

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The global interest in reducing CO2, as demonstrated by carbon neutrality, is growing in order to achieve a low-carbon society. Electronic packaging industry is seeing the importance of SnBi-based low-temperature solder (LTS) as it can reduce CO2 emissions during the assembly process.
While the soldering temperature of conventional SnAgCu solder is approximately 250℃, the temperature of SnBi-based low-temperature solder is approximately 170℃, enabling processing temperatures as low as 80℃. Despite the possibility of low-temperature assembly, SnBi-based low-temperature solder poses specific challenges and its use in the market has been limited.
The issues with SnBi-based low-temperature solder include the reliability of solder joints and the non-coalescence of BGA balls and solder paste known as HiP (Head-in-Pillow). Furthermore, in recent years, there has been an increased focus on electrical reliability, including electromigration, which is not exclusive to SnBi-based low-temperature solder.
This study presents the research results on the aforementioned phenomena from the perspective of SnBi-based low-temperature solder.

Author(s)
Ukai Ryuji, Kazuya Kitazawa, Takahiro Matsufuji, Masato Shimamura, Derek Daily, Takahiro Nishizaki, Ayano Kawa, Yoshinori Hiraoka
Resource Type
Technical Paper
Event
IPC APEX EXPO 2024

Advancements in Solder Paste Printing: Cleaning Compatibility Assessment of Jettable and Screen-Printable Pastes for Complex Electronics Assemblies

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Solder paste jetting is a popular and innovative method for applying solder paste in electronic assembly, especially for modern, miniaturized, and complex electronic assemblies. This technique provides several advantages over traditional solder paste printing methods. Compared to solder paste printing, solder paste jetting allows for precise control over the volume of paste deposited, as well as capability to print on various materials like flexible substrates, within cavities, and on top of previously placed components easily, without the need for custom made step stencils. Moreover, solder paste jetting minimizes the need for movement on z-axis there by enhancing the deposition speed. In addition, jetting improves the ability to deposit solder paste onto surfaces of varying heights.
Due to the inherent customization of depositions with jetting solder pastes, these materials are often used in conjunction with stencil-printable solder pastes in the same process line. Successful integration of jetting and stencil printable solder pastes in the same assembly line requires careful attention to formulation compatibility. Any formulation changes which will alter the characteristics of the two solder pastes in question, especially with respect to reflow and cleaning, can either result in added process costs or yield failures.
In this paper, the cleaning compatibility of jetting and compatible printing solder pastes will be analyzed. The paper will first outline the solder pastes selected for the cleaning compatibility study. Four pastes were selected in total: one no-clean stencil-printable paste, one no-clean jettable paste, one water-soluble stencil-printable paste, and one water-soluble jettable paste. The paper will then outline the different cleaning chemistries that were tested on these four pastes, all four pastes tested individually. The paper will discuss the process for assembling and cleaning the test boards, as well as the visual inspection performed for each component after shearing, according to IPC standards. Finally, the paper will discuss the results of the visual inspection, ion chromatography, and surface insulation resistance (SIR) testing to determine the best cleaning chemistry scenarios for each of the pastes in question.

Author(s)
Kalyan Nukala, Evan Griffith
Resource Type
Technical Paper
Event
IPC APEX EXPO 2024

Laser depaneling is a relatively clean separation process but nevertheless the knowledge of potential influence factors on the technical cleanliness is of central importance to find the optimal layout for demanding applications. Especially in industry sec

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Continuous pursuits for higher data rate, larger network capacity, lower latency communication, and better energy efficiency have motivated the rapid development of high-frequency communication technologies in recent years. Owing to the skin effect, the alternating electric current (AC) tends to distribute to the outer of a conductor in high-frequency transmission, such that the surface roughness of interconnects becomes an indispensable factor of the signal transmission characteristics. The focus of this study was to quantitatively investigate the effect of Cu-foil roughness on the signal transmission characteristics at mmWave frequency bands. The signal loss on differential striplines with different Cu-foil roughness was simulated by the Groisse and Huray models through using a 3D electromagnetic simulation software (HFSS). Furthermore, experimental measurements were conducted by using a vector network analyzer (VNA) to characterize the signal characteristics arising from different surface roughness, so as to validate the numerical simulation results. This quantitative analysis not only advanced our own fundamental knowledge in surface modification of the high-frequency materials but is greatly beneficial to the development of the 5G communication technologies. Detailed analyses on the high-frequency signal transmission performance of the differential striplines made of different Cu foils will be presented in this paper.
Keywords: 5G, HFSS, Roughness effect, Cu foil, Huray model, Groisse model.

Author(s)
Ying-Chih Chiang, Cheng-Yu Lee, Yu-Hsun Chang, Yu-Xuan Wen, Chun-Jou Yu, Wei-Ling Chou, and Cheng-En Ho
Resource Type
Technical Paper
Event
IPC APEX EXPO 2024

Technical Cleanliness of FR4 Substrates and its Influence Factors for Laser Depaneling

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Laser depaneling is a relatively clean separation process but nevertheless the knowledge of potential influence factors on the technical cleanliness is of central importance to find the optimal layout for demanding applications. Especially in industry sectors such as automotive and medical technology, technical cleanliness is one of the key requirements to ensure a reliable and secure function of the PCB and consequently the product. This paper presents an in-depth analysis of the particle contamination for different laser variants, cutting strategies and panel designs. Therefore, the panels have been processed with a tab and full cut as well as with the target for maximum performance and maximum cleanliness of the cutting edge on three different laser systems. In addition, design changes have covered different material thicknesses of the panel. The particle examinations comprise a particle extraction and subsequent analyses with optical light analysis as well as optical particle counting. The results of the measurements are verified against standards for technical cleanliness in the automotive (VDA19.1/ISO 16232) and medical industry (USP 788). This paper is examining in how far these fundamental standards can be achieved for all observed laser variants, designs and cutting strategies by identifying the largest metallic and non-metallic particles as well as counting and grouping the particles regarding their size. In addition, the authors are investigating the correlation of those variable factors and their impact on the level of technical cleanliness, allowing recommendations for the design of printed circuit boards to be derived from it.

Author(s)
Patrick Stockbruegger, Jim Greene
Resource Type
Technical Paper
Event
IPC APEX EXPO 2024

Research On Influence Factors Of Expansion And Shrinkage Compensation For Multilayer PCB

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The multilayer PCB is prone to poor expansion and shrinkage due to the influence of high temperature and high pressure during lamination process, which may cause risk of abnormal quality. The traditional method is to estimate the compensation value manually, which has low efficiency and great influence of human factors. The quantitative relationship between the compensation value and the expansion and shrinkage value is also unclear. In this context, this article establishes the base material expansion and shrinkage control index system, and uses descriptive statistics, correlation analysis, scatter plot and trend line analysis to carry out qualitative and quantitative analysis on the influencing factors and compensation ratio of expansion and shrinkage for different layers PCB, so as to effectively control bad expansion and shrinkage to improve production efficiency.

Author(s)
Wu Weihui, Chi Fei, Duan Shaohua, Xia Yunping, Guo Quan
Resource Type
Technical Paper
Event
IPC APEX EXPO 2024

Study of Copper Thickness Distribution in Through Hole at the Early Stage of Copper Filled Plating

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In laptop and tablet CPU/GPU applications, package thickness tends to be thinner since it brings lighter weight, lower product thickness, and shorter interconnection distance. To decrease package thickness, several parts of the package structure can be considered, such as bump height, ball height, die thickness, and substrate thickness. This study focuses on the thickness reduction of the substrate core.
The copper-filled plating technique will be used to fill the through hole instead of resin plugging when the substrate core becomes thinner, from over 400 μm to below 200 μm. However, during the copper-filled plating process, through hole opening tends to be closed earlier than through hole center due to the nature of electroplating. Consequently, voids are easy to form, causing delamination and crack risk during package reliability tests when the void area is too large or the barrel thickness is not enough. This research mainly explored copper distribution at the early stage of plating since it is important for minimizing void size and controlling barrel thickness. Various combinations of flow rate and current density have been designed to have different throwing powers and interactions with additives. From the results, uniform copper distribution and secured barrel thickness with low current density and high flow rate conditions were demonstrated. At the same time, successful inhibition of copper deposition around the through hole opening lets plating chemicals reach the center of the through hole. Therefore, void size can be minimized to lower the risk of package reliability failure.

Author(s)
Barry Zeng, Rick Ye, Yu-Cheng Pai, Yu-Po Wang
Resource Type
Technical Paper
Event
IPC APEX EXPO 2024

Reflow Soldering Performance Improvement of Polymer Aluminum Electrolytic Capacitor

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The reflow soldering performance of polymer aluminum electrolytic capacitors have a direct impact on their electrical performance. By analyzing the mechanism of capacitor bulges, improve the composition materials and production process, to enhance the high-temperature resistance performance, and reduce the risk of capacitor bulges.

Author(s)
Yingfeng Yu, Xinggao Huang, Yanhao Zhu, Fulin Zeng
Resource Type
Technical Paper
Event
IPC APEX EXPO 2024

Effect of Soft Touch Caused by Manual Handling on Substrate Warpage

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Flip chip BGA, interconnect with semiconductor chips and mainboards, to serve the interconnection of electronic products. This paper is about the study of one of the important warpage modulator in flip chop BGA product. When flip chip BGA interconnects with semiconductor and mainboards, assembly problem can occur by substrate warpage caused by thermodynamic behavior and incoming substrate warpage, CTE mismatch and other noise factor. During assembly process, unexpected warpage behavior can make open or short problem. The warpage of flip chip BGA is made by thickness imbalance, thermal process, mechanical damage and assembly condition. In advanced technology of manufacturing process, all process apply full automation and optimize to thickness control and it can improve a thickness imbalance, thermal behavior and mechanical damage by machine. But in sudden case of machine trouble, operator need to take off the panel by manual and it can make the soft touch of the panel. This study is about how soft touch can affect flip chip BGA product warpage. In case of horizontal soft touch of the panel, the combination of gravity force and product’s weight can make panel warpage and it can make substrate warpage. The thermal reflow test result shows that the increase of soft touch shows increase of abnormal behavior by 0 → 7 →16 →22 EA, when soft touch 0 → 1 → 2 → 3 times increase. This result shows soft touch of the panel can make unexpected assembly open or short problem. From this simple experiment, the effectiveness of soft touch is most important when flip chip BGA manufacturing process.

Author(s)
Zook Kim, Bong-wan Koo, Jinkyu Hong, Bongki Song
Resource Type
Technical Paper
Event
IPC APEX EXPO 2024

Advanced Ferric Sulfate Differential Etching: Meeting the Challenges of Electronics Miniaturization

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In the pursuit of ever finer lines and spaces to advance technology's power and efficiency, the substrate and substrate-like production processes must adapt to meet these demands while carefully considering procedural interdependencies. Traditional flash etching, essential for removing the seed layer after pattern plating in Semi-Additive-Processing (SAP) and advanced Modified-Semi-Additive-Processing (aMSAP), presents challenges like undercuts, increased roughness, and trace geometry distortion. These issues are particularly pronounced as conductor size decreases. Hence, the primary objective is to achieve a high etching rate on the seed copper while minimizing damage to the conductor, often referred to as the etching ratio.
However, economic constraints introduce an added layer of complexity. More viable base chemistries, such as ferric sulfate etchants, tend to be costlier in terms of raw materials and dosage requirements. Therefore, cost-effective regeneration measures become imperative to mitigate the adverse commercial impact associated with these solutions. Additionally, specific additives are required to control the etch rate, etch ratio, and working window of the overall flash etching process.
In this paper, we introduce a novel ferric sulfate differential etchant designed to address these multifaceted challenges. We delve into its function and performance, offering insights into how it can serve the substrate and substrate-like production processes by providing an effective, cost-efficient, and environmentally friendly solution to meet the evolving demands of modern technology manufacturing.
Key words
Flash etching, differential etching, seed layer etching, mSAP, Modified-Semi-Additive-Processing, SAP, Semi-Additive-Processing

Author(s)
Christopher A. Seidemann, Manuel C. Galvez, Fabian Michalik, Thomas U. Hülsmann, Andry Liong, Josef Gaida, Cedric Lin, Ting Xiao
Resource Type
Technical Paper
Event
IPC APEX EXPO 2024

The Surface Treatment for Semiconductor Substrate Using Low-Temperature Synthesis of Few Layer Graphene

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The protection of metallic substrates from reactive environments is necessary for semiconductor packages, which are mainly made of copper metal. Conventionally, plating with novel metals such as silver or gold is used. In this case, due to the high cost of novel metals, the process becomes complicated, such as plating only the wire bonding part. In addition, since plating is carried out using a wet process, it requires a space for storing the plating solution. This leads to the disadvantage of increasing the facility area needed to perform a continuous process.
Recently, graphene used for surface protection of metals has been grown using chemical vapor deposition (CVD) at 1000 ℃. However, this method has several negative effects, including size deformation and reduction in hardness of the metal substrate due to the high-temperature synthesis.
Here, we demonstrate the growth of few-layer graphene films using low-temperature plasma-enhanced chemical vapor deposition (PECVD) to protect the metallic substrate from air oxidation without causing any physical degradation to the substrate. The structural characterization, focused ion beam (FIB)-Scanning electron microscope (SEM), Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS) studies show that metal surfaces are well protected from oxidation even after an accelerated oxidation evaluation of 85°C and 85% RH for 5 hours.

Author(s)
Min Park, Suyeon Son, Hyunji Yoon, Hosang Yoo and Jin-Woo Lee
Resource Type
Technical Paper
Event
IPC APEX EXPO 2024