Influence of Process Parameters on Inkjet Printing of Silver Conductive Traces for Digital Additive Manufacturing of Flexible Electronics
The results of a NextFlex project addressing barriers that are preventing inkjet printing from being adopted for prototyping and volume manufacturing of printed circuits, are presented. These barriers include resolution, thickness, reliability and endurance. Silver conductive nanoparticle inks were evaluated with Konica Minolta 512-SH industrial printheads using the PiXDRO LP50 printer platform. These 512-nozzle printheads have a nominal drop volume of 4 picoliters, which corresponds to a drop diameter of ~20 um. The focus was on determining process parameters that enabled printing of narrow and continuous traces in both the in-scan and out-of-scan directions. Treatment of the substrate by wiping with isopropanol, and varying the substrate temperature, drop spacing and printing speed were investigated, and resulted in the demonstration of two silver conductor print settings, for an ink that was developed for this printhead. Trace widths of 50-60 um and 60-70 um were demonstrated on PET substrates at 70 °C substrate temperature for 1-pixel-wide lines in the in-scan and out-of-scan directions, respectively, while diagonal traces were even narrower. The trace width could be controlled by having traces with 1, 2 or 3 pixel width. The resistivity of the annealed traces was determined to be ~2 times that of bulk silver, with excellent adhesion to the PET substrate. When printing with a new printhead and ink, even very narrow traces were printed with high yield. Procedures were establishedfor achieving reliable operation of the ink and printhead over 6 months, after which nozzles began to become non-jetting. Finally, inkjet printing of the NextFlex A15 Arduino-Compatible Microcontroller was successfully demonstrated, including the die-attach section, which has the narrowest features and spacing. This indicates that inkjet could potentially replace screen printing and laser machining processes that are currently used for printing this device.