Evaluation of Solder Pastes for Flux Residue Mitigation in Cleaning Machines*
Recently new semi-aqueous in-line cleaning machines (CM) were installed; however, the associated increased volumes of circuit card assemblies (CCAs) being cleaned after SMT surface mount technology assembly resulted in correspondingly more solder paste residue or “goo” building-up on cleaning machine wash / rinse tank surfaces and “gumming-up” sump-pumps, causing sensor failures and interrupting production. Moreover, what remains is very stubborn to remove during preventative maintenance (PM). This goo is attributed to the presence of a plasticizer or flux softening additive in the current solder paste, which is not very soluble in cleaning solutions, and which further concentrates in the non-volatile residues (NVR) or % solids that precipitate / accumulate on cooler surfaces, rather than rinsing away with the other flux constituents. The “no-clean” solder pastes initially used by commercial industry attributed excessive electrical probe test contact fails from the “hard” flux residues remaining on the test pads, since the no-clean solder pastes are not cleaned or removed from the test pads. As a result, a rubber-based softening agent was added to render the flux residue on test pads more probe penetrable for electrical testing. Conversely, the current manufacturing site cleans-off the “no-clean” solder paste flux residue required for subsequent conformal coating adherence for aerospace / defense applications, and therefore does not need a softened flux residue for probing, since the flux residue is cleaned-off the test pads before electrical testing. Solder pastes with and without the softening agent were comparatively evaluated for effects on solder paste volume printed and solder solidified after reflow, ionic cleanliness, solder-joint shear strength, microstructure, IMC intermetallic thicknesses and viscosity on test vehicles and production products.