Conformal Coatings: State of the Industry Versus State of the Art
The excellent IPC-TR-587 technical report, ‘Conformal Coating Material and Application ‘‘State of the Industry’’ Assessment’ delivers the results of a recent major study on conformal coating, outlining an IPC study of major conformal coating types, coating application techniques, and coating cure technologies, characterizing the final film thickness on common component surfaces. It highlights that the nominal thickness applied is not particularly representative of the thickness or coverage of conformal coating materials on the various metallic surfaces. In many cases, the film thickness, although visually not zero, was below the limit of measurement.
In most manufacturing specifications, conformal coating thickness is specified as the thickness of the final polymer film on a flat, unencumbered surface of the assembly, however conformal coating thickness on other assembly and component surfaces is usually not characterized.
In this study, we compare the condensation resistance performance of assemblies coated with state of the art materials to those used in the state of the industry materials. The ‘no-clean’ SMT assemblies were subjected to controlled condensing environments using the National Physical Laboratory’s (NPL) static chamber method, relying on suppressing the temperature of the test board below the dew point, whilst simultaneously measuring Surface Insulation Resistance. Six different coatings were applied and cured, using a variety of common application methods – the same methods used in the state of the industry report, at normal nominal thicknesses, as measured on witness coupons. The coatings are assigned a Coating Protective Index (CPI) score based on their ability to maintain the SIR value of each test site above the widely used 100MΩ pass/fail criterion. A board from each coating set was extensively cross-sectioned after the condensation testing and examined for coating thickness and coverage, to understand how thickness, coverage and the inherent physical material properties combine to determine the Coating Protective Index.
The same 6 coatings were applied to SIR test coupons NPL TB33A (400μm lines, with 200μm spacings) at the same dry thickness. Coupons were tested with and without the same reflowed no-clean paste solder used in the condensation assembly. The SIR was measured throughout a 1000 hour experiment at 85°C/85%RH, a common compatibility test often performed in the automotive industry, to understand the influence of the solder paste / coating compatibility on the coating protective index achieved during the condensation testing.
In the final part of this experiment, the same six coatings were applied to conventional two-dimensional test boards (with and without solder-paste) at the same dry-film thickness, and subjected to immersion in deionised (DI) water at 50V, whilst the coatings resistance was calculated by measuring the leakage current. This allows the comparison of SIR values from condensation experiments with immersion experiments, to better understand whether immersion testing could be a faster & more predictive indicator of coating performance in harsh environments.