Atmospheric Plasma Surface Engineering of Printed Circuit Boards: A Novel Method to Improve the Adhesion of Conformal Coatings
Conformal coatings are essential components for the microelectronics packaging industry. These functional coatings aim to protect electronic circuits from environmental factors such as heat and moisture. Typical coating formulations involve the use of epoxy, urethane and acrylic chemistries on polymer printed circuit boards (PCBs) leading to poor adhesion and failure to form void-free uniform coatings that follow the PCB skyline contour.
Plasma treatment is a novel method to increase the adhesion strength of the conformal protective coatings to PCBs through the removal of residual organic contaminants and surface activation. Poor adhesion can be a result of: i) incompatible materials, such as bonding polymers, ii) process residue: contaminants from fluxing, soldering and chemical treatments and iii) handling and storage conditions: fingerprints and dust. Plasma treatment under atmospheric pressure plasma (APP) conditions has emerged as an alternative solution for completely assembled PCBs which does not require a vacuum-based system. APP processes are fast and can be used for the treatment of selective areas of the board. The technology utilizes a dry gaseous medium and does not involve any harsh liquid solvent chemistries. Air-based APPs contain gaseous species that can react and remove organic surface contaminants very rapidly. Furthermore, they can be instrumental in the chemical functionalization and activation of the surface. In this paper, case studies from the application of air-based APPs for the cleaning of PCBs and the improved adhesion of conformal coatings will be presented.