Effect of Toughening and E-Glass Sizing on Fracture Toughness and Delamination in High Thermal Stability Electrical Laminates
In this work we report results of the fracture toughness of a high thermal stability resin system toughened by The Dow Chemical Company proprietary particulate-type toughening material. Results show a significant improvement in the fracture toughness with minimum impact on other thermomechanical properties such as Tg and Td. Because delamination in electrical laminates is a critical failure mechanism observed in such systems,we also investigated the potential synergistic impact of the toughening material (FORTEGRA™ 351) and glass sizing on adhesive properties of the laminate board. Results showed improvements in both shear and tensile strengths of the test vehicles with the addition of the toughener for two different glass finishes. A drilling test showed significant delamination failure for a non-toughened board as observed by a large halo around the drill-hole,and a punch test yielded similar results. Further,it was shown that copper peel strength improved with the addition of the toughener for the two different glass finish types studied. These results are important because they show that use of the toughener and appropriate choice of glass-finish will significantly improve the thermomechanical integrity of high thermal stability test vehicles during downstream part fabrication processes.