In an effort to reduce volatile organic compound (VOC) emissions within our environment,policymakers
have encouraged and/or mandated that electronics manufacturers change from alcohol-based VOCcontaining
fluxes to water-based VOC-free flux alternatives. As a result,the use of VOC-free fluxes is
growing throughout North America,Asia and Europe.
The purpose of this study is to explain several factors relating to the use of a VOC-free flux in the soldering
process and their impact on testing and product reliability. These factors include; the effect of varying types
of acids used in flux formulations and their impact on Ion Chromatography (IC) and Surface Insulation
Resistivity (SIR) test results and weak organic acids (WOA) solubility and their influence on the electrical
integrity of assemblies. This paper shall provide valuable insight into the outcome of acid-solvent
interactions.
The transition to VOC-free fluxes from alcohol-based fluxes can be a challenge and may require several
changes in the assembly process. Compounding these challenges is the increased use of lead-free alloys
with the looming expiration of the RoHS exemptions. Additional pressure has been placed on solder flux
manufacturers to meet the newer,more restrictive ionic test requirements and updated SIR test criteria.
AIM Product Development Group’s study consisted of using several organic acids,each individually
incorporated into both a generic VOC-free and a generic alcohol flux base. Half the test boards were sent
out for IC testing per IPC-TM-650 2.3.28 to determine the level of WOA. The other half were sent for SIR
testing per IPC 2.6.3.7. The fluxes were also run on a wetting balance to determine solderability
differences. The test results of the alcohol-based fluxes were not included in this study.
Additional important considerations related to VOC-free fluxes addressed in this paper include wetting
characteristics,organic solvent characteristics,the importance of a flux’s collapsing foam head,issues
related to corrosivity,shelf life,manufacturability,handling and storage. All of the aforementioned issues
were taken into consideration when developing the flux base for this study.