Effects of Reflow Profile and Thermal Shock on Intermetallic Compound Thickness for SnPb and SnAgCu Solder Joints
During the solder reflow processes many reactions occur. There is the reduction of oxides on the metal surfaces,metal dissolution,wetting to different surfaces,and intermetallic compound formation between the bulk solder and the metals being soldering. The intermetallic compound (IMC) is necessary for good solder interconnections. However an excessive IMC may raise solder joint reliability concerns due to its brittle nature. Therefore,a proper IMC thickness is critical for solder joint integrity. The amount of IMC formation is a function of reflow time (Time above Liquidus) and temperature (Peak Temperature). In a Pb-free process,both reflow temperature and time can increase,possibly increasing the thickness of intermetallic formed. During thermal shock,thermal aging or thermal cycling,IMC will grow as well.
The purpose of this study was to investigate the effects of reflow time,reflow peak temperature,and thermal shock on IMC thickness. Four different sizes of chip resistor (1206,0805,0603,and 0402) were attached to OSP surface finish boards with Sn-3.0Ag-0.5Cu (SAC305) solder alloy paste. Traditional Sn-37Pb eutectic solder paste was used as the control in this study. Nine reflow profiles for SAC 305 and nine reflow profiles for SnPb were developed with three levels of peak temperature (12°C,22°C,and 32°C above solder liquidus temperature,or 230°C,240°C,and 250°C for SAC 305; and 195°C,205°C,and 215°C for SnPb) and three levels of time above solder liquidus temperature (30 sec.,60 sec.,and 90 sec.). Half of the test vehicles were then subjected to air-to-air thermal shock conditioning from -40 to 125°C for 500 cycles. IMC thickness was measured using Scanning Electron Microscopy (SEM) with Energy Dispersive Spectroscopy (EDS). The results show that the IMC thickness increases with higher reflow peak temperature and longer time above liquidus together with thermal shock testing.