Running Lead Free Reflow Profiles Without Nitrogen
The widespread use of SAC-based (SnAgCu) lead-free solder paste drives the industry toward reflow profiles that are
considerably longer than those used for lead-bearing products. This is due to the narrower process window. The latter is a
result of the higher reflow temperatures on one hand and the limited thermal resistance of the current generation of electronic
components on the other.
The minimized process window requires a significant reduction of ?-T’s between the small and large components. The most
common way to minimize ? -T’s is to extend the soak or ramp before the reflow phase.
It is well understood that the thermal breakdown of most materials is impacted more by prolonged dwell times at higher
temperature levels rather than the temperature level as such. The consequence,for the solder paste,is the thermal breakdown
of the organic material resulting in the loss of the protective flux blanket,finally yielding inferior reflow performance.
Industry sectors that typically have assembly designs with major differences between small and large components have the
option to successfully reflow these assemblies in a Pb-free process with the use of nitrogen to protect the solderability of the
assembly.
Since electronics manufacturing is a cost-driven industry,however,the use of nitrogen is a highly undesirable cost factor.
This paper describes the development and implementation of SAC-base Pb-free solder paste for use in reflow-processes with
extended temperature profiles,but without nitrogen.
It explains the need for flux systems in this generation of solder paste based to incorporate organic materials of longer
molecular chain length. Thermal resistance studies show the advantages of these materials. Also,solutions for the enhancing
the mobility of these materials are provided,impacting the printing properties of SAC-based solder paste.