The technology shift toward higher performance (low Dk,low Df,faster signal speeds) resin materials for high reliability
high layer count multlayer interconnect devices is moving rapidly. PWB fabricators are discovering that the bond strength
between the copper circuitry and these resin systems is not as reliable with reduced oxide bonding treatments. It has been
shown in the market place that reduced oxide processes are being replaced by new process developments for a variety of
reasons that will be explained. In addition,increased use of ENIG (electroless nickel-immersion gold) and immersion tin
processes is causing adhesion failures of some liquid photoimageable soldermasks. This paper will explore the mechanism of
resin adhesion to copper surfaces and provide a discussion on the interaction of the key process parameters (etch rate,organic
coating content,sulfuric acid concentration,copper loading in solution) on the process performance. Reduced oxide bonding
technology will be the benchmark comparison for the performance of the alternative technology. Bond strengths for a variety
of high performance resin systems will be measured. These materials will include high Tg epoxy FR-4,cyanate ester,BT,
polyimide,PPE and PPO resins. In addition to measuring bond strengths,other methods including solder float and T-260
time to delamination will be utilized to compare results. Additional IPC recognized test methods would be employed to
compare the performance and reliability of the organo-metallic process to reduced oxide. The paper will conclude with a
discussion on improving soldermask adhesion with a modified organo-metallic surface treatment process.
Author(s)
Michael Carano,Lee Burger,Al Kucera,Roger Bernards