Erosion of Copper and Stainless Steels by Lead-Free-Solders
An issue that has emerged from the increasing use by the electronics industry of lead-free solders in mass production wave
soldering is the erosion of the copper of printed circuit board patterns and component terminations and the stainless steel of
the wave solder bath. In the study reported here the wetting and erosion of copper and Type 304 stainless steel by two widelyused
lead-free solders,Sn-3.0Ag-0.5Cu and Ni-stabilized Sn-0.7Cu,was compared with that of Sn-37Pb and Sn-0.7Cu with
and without the addition of phosphorus antioxidant. The rate of dissolution of copper by the Ni-stabilized Sn-Cu alloy was
found to be lower than that of pure Sn-37Pb alloy while that of the Sn-3.0Ag-0.5Cu and Sn-0.7Cu alloys was higher. The
addition of phosphorus increased the copper erosion rate of both lead-free alloys well beyond that of Sn-Pb. The rate of
erosion of stainless steel by lead-free solder was confirmed as faster than that of Sn-Pb eutectic solder and phosphorus was
found to promote the wetting that precedes erosion. The rate of erosion of stainless steel by the Sn-0.7Cu solder was
significantly slowed by the addition of nickel.