A Lower-Temperature Lead-Free Solder Paste for Wafer-Level Package Application that Outperforms SAC305
An In-containing mid-temperature solder paste (MTS) has been developed and successfully used in mobile phone board-stack soldering with a 200°C peak temperature profile [1]. It is now being tested for a wafer-level package (WLP256) application using reflow profiles with peak temperatures ranging from 200°C (P200) to 240°C (P240). SAC305 was used as the control, which was reflowed using a traditional lead-free soldering profile (P240). With the constant paste-to-ball volume ratio of 1:4, the joint morphology changed with the reflow profiles. Under the 200°C peak reflow, hybrid joints were formed, in which the mixing zone, dominated by the MTS, was present at the PCB side while the area above the mixing zone maintained the original SAC305 morphology. Inside the mixing zone, In was present in the form of a InSn4 (γ) phase, Sn(In) solid solution, and likely, In4Ag9 particles. Increasing the reflow peak temperature to 210°C (P210) and above, the homogeneous joint was formed, which indicated the fully-merged SAC305 ball with the MTS paste during reflow. The homogeneous joint morphology was similar to the traditional morphology of SAC305, in which an Sn dendrite was surrounded by a Ag3Sn precipitate network. In most likely existed in In4Ag9 participles and the Sn(In) solid solution. The temperature cycling test (TCT) was conducted with a -40/125°C and 20-minute dwelling profile. Regardless of the reflow profiles, the MTS outperformed SAC305 in TCT. The P210 profile forming the homogeneous joint, resulted in the best TCT performance, which was more than a 30% improvement than its counterpart using SAC305 paste. The other profiles also improved the characteristic life at least 11% more. Using the same reflow profiles, the MTS had also demonstrated that the drop shock performance (g-force >6000g) was at least comparable to or significantly better than SAC305, in which the P220 (220°C peak temperature) reflow, forming the homogeneous joint with the paste-to-ball volume ratio of 1:2, led to the best drop shock performance—more than 90% enhancement than SAC305. Although the reflow profiles impacted the performance, the failure modes remained similar to SAC305.