A new non-halogen flame retardant has been developed and is useful for a variety of high performance applications. This
non-reactive phosphorus-based material satisfies fire safety needs for a broad range of resins including epoxy,polyolefin,and
polyamide. The combination of excellent flame retardant efficiency,high thermal stability and exceptional electrical
properties is unique to this organophosphorus flame retardant and makes it a breakthrough technology for high speed,high
frequency use in fast growing wireless and wired infrastructures. Resin performance data,including formulations with
synergists,are presented in this paper.

Multi-layer organic laminates which make up over 90% of the present types of interconnecting substrates in today’s electronics can develop a loss of insulation resistance between two biased conductors due to a failure mechanism known as conductive filament formation. The probability of CFF is a function of temperature,moisture content,the voltage bias,manufacturing quality and processes,materials and other environmental conditions and physical factors. Filament formation typically appears to arise in two steps: a degradation of the resin/glass fiber bond followed by an electrochemical reaction. Bond degradation provides a path along which electro-deposition may occur due to electrochemical reaction. The path may result from poor glass treatment,from the hydrolysis of the silane glass finish and from mechanical stresses. Microscopic examinations of failure sites have shown that conductive filaments can be formed along de-bonded or delaminated fiber glass/epoxy resin interfaces,due to breaking of the silane bonds. The bi-functional silane molecules act as a link between the glass fiber and resin by forming a chemical bond with the glass surface through a siloxane bridge,whereas its organo-functional group bonds to the polymeric resin. The organosilane bonds are known to chemically degrade by hydrolysis. This paper will characterize the degradation of the interfacial bonds between the glass fibers and organic resin. Analytical technical techniques such as Nano-indentation are used to characterize the quality of the interface and follow the change in this interface as a function of absorbed moisture into the PCB.

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The portable electronics market has driven steep-slope growth for over a decade and continues to deliver amazing handheld electronic devices; manufacturers of these products are facing challenges they thought would be in the distant future: denser electronic substrates,more power demand and more heat to dissipate,stringent use conditions,and more importantly,demand for lower production cost.
Lowering production cost is critical to remaining competitive; hence the objectives become high “first pass quality” and low “returns for failed units.” There is high demand for manufacturing tools and processes that attain these goals.
Conformal coating is a cost effective process used to maintain the functionality of the electronic components inside a mobile device in harsh environmental conditions. This paper discusses recent developments in conformal coating that help enable the manufacturing process to meet the criteria for increased reliability at a lower cost,especially important for high production volume devices that command above average selling price.

The use of plasma processing in the manufacture of electronics is growing as we discover more and more applications for this technology. It is now common for plasma etching and cleaning to be used in multiple stages of the electronics manufacturing process. The introduction of new plasma polymerization methods and equipment has added new possibilities and applications for plasma.
Plasma polymerization is a unique and exciting new tool for our industry. Plasma polymerization is a simple,one step process that can be used to apply a thin,uniform film as a protective coating which requires no curing or the use of any solvents. The chemical structure and properties of the coating can easily be tailored to the requirements of the application by selection of the appropriate precursors and processing conditions. The protective coatings that can be deposited using plasma polymerization represent an opportunity for the industry to deliver new,more reliable products to the market.
This paper will discuss the plasma coating process and the equipment used. The application of this type of coating process to printed circuit boards and electronic assemblies and the results of tests to demonstrate the protection offered by these coatings will also be presented.

The thermal stability of silicone polymers,fluids and resins has been well documented and studied extensively. The high temperature performance of silicone adhesives and sealants used for electronics applications has only moderately been investigated. This report documents the effects of very high temperature exposures to electronics-grade silicone adhesives and sealants for such properties as tensile strength,elongation,tensile modulus,weight loss,shrinkage,durometer,and lap shear adhesion. The goal of the work is to determine application “life expectancies” of the products as well as an extrapolated estimate of the Underwriter’s Laboratories’ “continuous use” temperature rating – the highest temperature at which a product is expected to lose no more than 50% of its original value for whatever key property degrades the fastest
Four different formulations of silicone adhesives and sealants were evaluated for high temperature stability. For these products,elongation was found to be the fastest degrading property among those tested. The data was found to fit a power curve of exposure temperature vs. time to reach a 50% loss of initial tensile strength and elongation to an R-squared value of 0.99 and to a linear fit in an Arrhenius plot to the same very strong fit. These plots could be used to closely estimate the effects ofHeat Aging on the material over a wide range of temperatures.

Circuit complexity and density requirements continue to push PCB fabrication capability limits. Component pitch and routing requirements are continually becoming more aggressive and difficult to achieve in good yield with current fabrication strategies. The trend is to bring the PCB closer to the density requirements currently required for semiconductor packaging. The ability to place interconnecting vias in any location on any layer is crucial to PCB fabricators in meeting this high density interconnect (HDI) trend.
The two fundamental elements in any type of PCB,conductors and dielectrics,both have to be considered when building “any layer” HDI. These PCB’s have specific challenges for processing while maintaining thermal and electrical performance. Careful consideration of the interplay of the fundamental elements is critical to fulfilling all of these requirements.
New methods and materials designed specifically with these challenges in mind are becoming available for building HDI
Using materials specifically designed for HDI PCBs can significantly reduce the challenges producing these boards. However,along with easing the challenges of fabrication,these materials must also demonstrate the right combination of properties to meet electrical and thermal requirements while also being reliable. Validation of these new technologies is currently underway.

Eutectic god-tin (Au80Sn20) is widely used as the die-attach material for making radio-frequency (RF) and microwave devices. The metallic bonding is typically achieved by soldering using a gold-tin preform in a forming gas containing hydrogen (H2) and nitrogen (N2) to a peak temperature at 300°C. The performance and reliability of the devices are strongly dependent on the quality of the die-attach layers. It is always expected to make the die-attach layers as free of voids as possible since the voids are poor thermal and electrical conductors and also are stress concentration centers. There are three major causes for void formation,which include poor solder wetting due to surface oxides,vapor out-gassing by flux decomposition,and gas entrapment from preform melting. It is known that the gas entrapment is more significant for larger dies and can be managed by gas evacuation before the melting of the solder. However,a good fluxless and oxide-free technology for metal die attach is still lacking. The organic fluxes used in conventional soldering not only induce void formation but also leave residues,which contaminate the dies and are corrosive. In addition to being costly and inconvenient to clean,the residues at the bonding interfaces of the die-attach layer are trapped,thus degrading interfacial bonding over time. The current study introduces a novel technology of using electron attachment (EA) to activate H2 diluted with N2 for fluxless die attach. EA is a new concept for ambient-pressure gas activation,which brings several advantages compared with plasma-based gas activation. Results obtained in this study demonstrate that solder oxides and organic contaminations on the surfaces to be bonded can be effectively removed by EA-activated forming gas,which leads to better solder wetting compared to flux-based process. The EA technology also shows a feasibility of reducing peak temperature of die attach from 300°C to 290°C,thus minimizing high-temperature induced damages. These advantages are believed to be attributed to the higher surface tension of the oxide-free molten solder compared with that of an organic flux,thus leading to a larger wetting force. As demonstrated in the study,the fluxless and oxide-free technology using EA has made it possible to achieve a high quality die attach with zero or near-zero (= 5%) voids.

•Voiding of QFN a concern due to large thermal pad,low standoff,and many thermal via
•Divided thermal pad preferred,with SMD better than NSMD
•This work focus on systematic study on effect of SMD divided pad on voiding

In this work we report results of the fracture toughness of a high thermal stability resin system toughened by The Dow Chemical Company proprietary particulate-type toughening material. Results show a significant improvement in the fracture toughness with minimum impact on other thermomechanical properties such as Tg and Td. Because delamination in electrical laminates is a critical failure mechanism observed in such systems,we also investigated the potential synergistic impact of the toughening material (FORTEGRA™ 351) and glass sizing on adhesive properties of the laminate board. Results showed improvements in both shear and tensile strengths of the test vehicles with the addition of the toughener for two different glass finishes. A drilling test showed significant delamination failure for a non-toughened board as observed by a large halo around the drill-hole,and a punch test yielded similar results. Further,it was shown that copper peel strength improved with the addition of the toughener for the two different glass finish types studied. These results are important because they show that use of the toughener and appropriate choice of glass-finish will significantly improve the thermomechanical integrity of high thermal stability test vehicles during downstream part fabrication processes.