Examination of Glass/Epoxy Interfaces in Printed Circuit Boards
Most manufacturers of electronics grade glass fiber reinforcement used in today’s laminates apply treatments to enhance the bonding strength between the inorganic e-glass and the epoxy matrix which surrounds it in the laminate structure. These treatments,when properly formulated and applied on the glass fibers help to prevent glass-resin delamination due to mechanical stresses or due to thermal excursions during the laminate lifecycle. The thermal excursions can include multiple reflow cycles followed by wave soldering and in some common circumstances a cycle or two of rework. However,such laminates continue to develop glass-resin delamination that promotes a form of electro-chemical migration that leads to a loss of electrical insulation resistance between opposing biased conductors. This phenomenon is commonly known as conductive anodic filament (CAF). The glass-resin delamination can also contribute to a reduction in the mechanical flexural strength,which is not the focus of the present paper. The probability of CAF failure is a function of temperature,moisture content,the voltage bias,manufacturing quality and processes,materials and other environmental conditions and physical factors. The present paper discusses the glass treatments and examines the effects of thermal and combined thermal/moisture exposure on the glass-resin interface. Atomic force microscopy is used for examination of sites to track the state of degradation and changes in the mechanical properties. Micro-Fourier transform infrared spectroscopy is used to track the progression and diffusion of the inter-penetrating network formed as a result of inter-diffusion between the glass-treatments and epoxy laminate material. The results of the studies are expected to show the progression of damage and provide unique quality assurance and failure analysis insights into this less reported contributor to printed circuit board quality.