The use of flexible circuit boards in the design and manufacture of electronic products has experienced a consistent and rapid growth over the last 15 years because their light weight and physical flexibility make it possible to combine electronics,packaging design,and styling to create exciting new consumer products. And as the capacity and pin density of electronic components has continued to increase,new demands are being created for flexible circuit boards. These new demands include the need for thinner copper on thinner flexible substrates with greater bending flexibility and durability.
The most common commercialized process today for the deposition of ultra-thin copper on flexible base materials is a vacuum sputtering process. In this process,there is a sputtered tie coat of chromium or other metals or alloys to improve the adhesion to the base,followed by sputtering of a thin layer,usually about 0.2 micron,of copper. Quite often the substrate is pre-treated with plasma to improve tie coat adhesion to the base material. This is often followed by the electro-deposition of copper to the desired final copper thickness. These products have been successful in the adhesiveless-copper-on-flexible substrate marketplace. However,the process is expensive because of the need for high capital cost vacuum deposition equipment,is energy intensive,requires the use of toxic metals,requires many processing steps,and is inherently single sided. In addition,the process requires additional processing steps beyond normal etching processes for the removal of the tie coat.
We are commercializing an innovative approach for metalizing flexible substrates. This new approach,which was developed
in the labs of SRI International (formerly Stanford Research Institute) is a non-vacuum process that eliminates the need for
expensive vacuum deposition,eliminates plasma treatment of base material,eliminates several expensive process steps normally associated with conventional copper coating techniques,and produces superior adhesion without the need for a tie coat. All of the process steps can be single or double sided,and have been implemented with a roll-to-roll manufacturing process. Flexible circuit materials made with this process can be used in most types of flexible circuit board manufacturing processes including subtractive and semi-additive methods. The copper deposited is ductile,and has good thickness tolerance. We have achieved outstanding adhesion to the base material along with good surface insulation resistance (SIR) and other pertinent properties. The process that has been implemented can produce coated copper with a thickness ranging from 0.1 micron to 18.0 micron. A variety of base materials have been studied with good results. These include polyimide,particle filled polyimide,liquid crystal polymers (LCP),polyesters,and composites. And the total process is inherently “greener” than existing materials and methods because of the elimination of most (99.95%) or all of the etched materials used in conventional subtractive and semi-additive processes today.
    Author(s)
              Sunity Sharma,Jaspreet Dhau,Naishadh Saraiya,Jerome Sallo,Alex N. Beavers