Tin Whisker Growth - Substrate Effect Understanding CTE Mismatch and IMC Formation
The hypothesis that the “whisker growth phenomenon” in electrodeposited tin is a re-crystallization process driven by stress
has gained popularity among leading research institutes and industrial laboratories. However,there exist varying opinions as
to the type of stress responsible for this phenomenon. Recently,various studies have demonstrated that compressive stress,
whether intrinsic or externally applied,is most likely the cause of whisker growth.
There are three main sources of compressive stress that a component finish experiences after plating. They are: stress
generated by intermetallic compound formation between the tin finish and the copper alloy substrate; mechanical stress such
as trim-and-form introduced in current manufacturing practice; and thermal stress generated by temperature cycling and
propagated into tin layer due to CTE mismatch among the constituent materials of a component.
It is well recognized that both IMC formation and CTE mismatch are largely affected by the substrate material and
underlayer/barrier between Sn and substrates,as well as aging conditions. In this paper,we attempted to understand the
relative contribution of stress generated from IMC and from CTE mismatch on various leadframe and connector substrates at
both isothermal and temperature cycling conditions. Ultimately,we hope to delineate the whisker accelerating factors to
provide input for the industry to derive a set of standard yet realistic whisker test methods.