Wetting of Fresh and Aged Immersion Tin and Silver Surface Finishes by Sn/Ag/Cu Solder

The wetting of alternative PCB surface finishes,including immersion silver (I-Ag) and immersion tin (I-Sn),by
Sn/Ag/Cu solder and Sn/Pb solder,was studied in this work,along with electroless nickel/immersion gold (Ni/Au)
and organic solderability preservative (OSP) finishes for comparison. Evaluation of wetting was carried out with
fresh boards and boards subjected to different pre-conditioning treatments which simulated the effects of aging,
storage and multiple reflow cycles. Selected conditions consisted of high temperature aging at 155°C for up to 6 and
12 hours,temperature-moisture exposure at 85°C/85%RH for 6,12 and 24 hours,and reflow treatments between 2
and 4 reflow cycles. Wetting was studied based on the IPC-TM-650 2.4.45 standard,by a wetting bar test,and by a
wave soldering test.
The results show that when the boards are fresh,the wetting of the I-Sn finish is excellent and comparable to that of
the Ni/Au finish,and the wetting of I-Ag is slightly better than that of the OSP finish. However,after the preconditioning
treatments,the wetting of the I-Sn finish degrades the fastest,whereas the wetting of the I-Ag and OSP
finishes decrease almost at the same rate after different pre-conditioning treatments,while the wetting of the Ni/Au
finish remains excellent through all the pre-conditionings treatments. In all cases,the wetting of surfaces is better by
the Sn/Pb solder than by the lead-free solder.

Author(s)
Minna Arra,Dongkai Shangguan,DongJi Xie
Resource Type
Technical Paper
Event
IPC APEX 2003

Board Finish Solderability with Sn-Ag-Cu

Lead-free soldering technology is still in its infancy with technical and cost issues posing major challenges for the
industry. It is expected that soldering in a nitrogen atmosphere might overcome some of the technical barriers and
provide soldered products comparable to those using conventional lead-containing materials processed in air. But
quantitative data regarding the soldering behaviour of lead-free solders under various atmospheres are sparse. As
part of an ongoing study on the effects of inerting on the solderability of lead-free alloys an examination has been
made of the solderability,as measured in a wetting balance,of three common board finishes using a 95.5/3.8/0.7
SnAgCu solder. The board finishes used were ENIG,HASL,immersion silver and a copper OSP. To simulate
typical lead-free soldering cycles the samples were subjected to multiple temperature cycles in a convection reflow
oven before solderability testing using a Multicore MUST II tester. A peak reflow temperature of 250°C and an R
flux was used for the ENIG and Ag finishes. The OSP finish performed poorly under these conditions and OSP
testing was done using a 235°C peak temperature and a 0.5% activated R flux. During testing the atmospheres were
controlled at levels of oxygen of 21% (air),10,000,1000 and 100ppm. Although inerting improved the solderability
of all three finishes,there were differences between the individual alloys. Aging by multiple reflow cycles adversely
affected the solderability of all finishes but the effects were less for ENIG than the other finishes.

Author(s)
Chris Hunt,Ling Zou,Sean Adams
Resource Type
Technical Paper
Event
IPC APEX 2003

The Importance of Cooling Rate in the Developing the Totally Controlled Reflow Process for Lead Free and Eutectic Tin Lead Processing

The impact cooling rates exert on the reflow process is identified. The trends in shear strength and the
microstructural evolution of the solder joints are described. Lead free (Sn/3.5Ag/0.7Cu) and tin lead (63Sn/37Pb)
assemblies on copper organic solder preservative (Cu-OSP),electroless nickel-immersion gold (ENIG),and
immersion tin (Imm Sn) surface finishes were considered in this experiment. A Differential Scanning Calorimeter
(DSC) was used to simulate the heating and the cooling cycles undergo by solder in the reflow process. The strength
values and the analysis of microstructure were documented using an Instron Machine and Scanning Electron
Microscope (SEM):
• Slower cooling rates result in the increased formation of the Ag3Sn and Cu6Sn5 intermetallics. These will form
both in the bulk solder as well as at the pad – solder interface. Faster cooling rates inhibit the growth of these
intermetallics.
• Aging results in joint fatigue thus reducing the shear strength of the joint. This is the result of solder migration
and increased intermetallic thickness at the solder – pad interface.
• Time above Liquidus impacts the intermetallic thickness at the solder – pad interface.
• Faster cooling rates result in stronger joints as observed in those samples with a Cu-OSP board finish. The
opposite trend is observed for samples assembled on Imm Sn and ENIG board finishes.
• Failure modes for the shear test depended on board finish. Imm Sn samples failed by pad lifting while ENIG
and Cu-OSP failed by cracking in the bulk solder.
• Profile type influences joint quality but is greatly dependent upon all reflow process parameters,especially flux
– profile compatibility.

Author(s)
Ursula Marquez,Denis Barbini
Resource Type
Technical Paper
Event
IPC APEX 2003

Multi-Stage Flux Filtration in Reflow Ovens

Flux management methods for reflow soldering have been debated for years. Current data suggests that multi-stage
filtration systems offer many benefits,particularly in dealing with the byproducts of new solder/flux paste
formulations. High system efficiencies result from targeting all areas of the oven,using multiple scrubbing units and
developing filtration units to capture volatiles released during the reflow process. These systems are also energy
efficient,require minimal facility resources and virtually operate maintenance-free by incorporating self-cleaning
cycles. This paper discusses these advantages in detail and shows the low cost of ownership that multi-stage flux
filtration systems can provide. The presented data is based on actual production performance within a mediumtohigh
volume reflow operation.

Author(s)
Jon Dautenhahn,Marc Apell,Tad Formella
Resource Type
Technical Paper
Event
IPC APEX 2003

Oven Characterization Using Machine Quality Management (MQM) Tools

Stability and repeatability are imperative in any
reflow oven today. If oven operation is not validated
periodically,all subsequent profiles and adjustments
are not reliable in finding or maintaining an optimum
reflow process window for products. This is
especially true for lead free where the actual process
window has shrunk to a fraction of what everyone is
used to when using eutectic solders.
Ovens have been validated using mock-up FR4
assemblies,where the assembly is wired with
thermocouples and used with a profiling unit.
Unfortunately,the thermocouples lift,the board
suffers warping and material degradation after only a
short number of passes through the oven. Stainless
steel and aluminum plates have been configured to
resemble a board,and are able to withstand repeated
thermal cycles. However the material is so alien
compared to FR4,the radically different thermal
conductivity of the material masks potential
weaknesses in oven design. If you want a true
characterization of all oven parameters,it’s important
to match these physical properties within a single test
tool. Therefore,to do proper thermal validation,it is
best to use a tool specifically designed for that job
rather than to try to create either type of vehicle
described above. The composites used to create the
pallet for thermal characterization and validation
equipment known generically as Machine Quality
Management tools (MQM) have highly insulating
properties similar to typical FR4 material as well as a
high tolerance for long endurance use in high
temperature environments.
For this experiment,we took a typical MQM tool and
investigated the performance of four different ovens.
The tool measured the uniformity of gas temperature
and the heat transfer characteristics and saved the
data from each oven which was downloaded into the
accompanying MQM software program for
comparison and analysis. Our goal was to find out
how easy or difficult it is to characterize specific
physical properties of a given oven design as they
relate to the soldering process and to see if the results
indicate a dramatic differences in oven performance,
specifically,the uniformity across the width and
length of the tunnel as well as the heat transfer
capacity.
Using an MQM tool,it was possible to characterize
specific physical properties of each oven to see if oven design significantly impacted the steady state
operation of the individual zones as well as the entire
heated length. We assumed the uniformity or lack
thereof in the measured air temperature along the
length of the tunnel and across the width of the tunnel
would have an impact on the ability to consistently
and uniformly heat the product to be run. The
difference in temperature as measured between the
air and the high mass sensors of the MQM tool
demonstrated the efficiency of each oven to transfer
heat,or heat transfer value. A higher heat transfer
value means tighter control over the reflow process.
This proportionality is related to the heat transfer
coefficient,however,is not the exact heat transfer
coefficient for any particular oven. Several tools exist
to characterize the heat transfer coefficient as well as
defining the portion of heating associated with
infrared energy.

Author(s)
Karl Fischbeck
Resource Type
Technical Paper
Event
IPC APEX 2003

Efficient Placement Performance Verification of Odd Form Assembly Equipment

One of the electronic assembly markets that has
been emerging in recent years is the automation
equipment associated with odd form component
placement and final product assembly. As with
insertion mount and surface mount equipment,the
procurement process of odd form equipment
typically includes having the machine provider
guarantee certain performance levels and provide
evidence from a machine qualification process that
the machine being shipped is actually capable of
performing to specification. Due to both the slower
tact times and higher component prices in many
typical scenarios (relative to most surface mount
and insertion mount applications),the sample sizes
and test hours required to verify odd form
equipment to the high quality levels that the
electronic assembly industry has come to expect -
with defects measurable in parts per million (PPM)
units - can be quite burdensome. Having to insert
tens or hundreds of thousands of parts during
machine qualification can be quite costly and timeconsuming.
For example,a test involving the
insertions of 20,000 parts with only one defect
would yield a performance estimate of 50 PPM.
But a test with this many real odd form parts would
be very costly.
One alternative method to demonstrate odd form
machine accuracy has relied upon placing surface
mount slugs instead of inserting odd form parts.
Slugs (pieces of glass with the image of an SMT
part etched on it,such as those defined in IPC-
9850),are easily placed on a board with sticky tape
and measured with a coordinate measuring
machine (CMM) in order to obtain very precise
variables data. The benefit of such a variables
approach (as opposed to a go/ no go “attribute”
approach,where each insertion or placement is
only characterized as good or bad,rather than being
precisely measured) is that a very small sample size
of parts can be placed in a slug run to gain a PPM
estimate with a high degree of confidence.
The downside to the slug approach is that these
parts are dissimilar from odd form parts in that they
cannot be inserted into holes,and even if they
could,without adhesive they would move around
after insertion,making the variables data for each
part incorrect. So this difference in the nature of
board assembly (between surface mount and odd
form assembly),combined with the fact that odd
form assembly equipment users use a wide range of
odd-shaped parts that are handled quite differently than slugs,has led us to consider alternative
approaches to estimating PPM that could either
replace or supplement the slug approach.
In this paper,a method used internally by Universal
Instruments Corporation to qualify its Polaris
assembly equipment to 50 PPM or better will be
presented. The method is statistics-based,and
involves insertion rather than placement. Yet it still
gives results,PPM estimates,comparable to slug
runs. This method will be shown to be quite
efficient and,since it requires no operator once it is
started,it is even less labor-intensive than a series
of slug runs. And it does not require the use of
CMM,so it could easily be replicated at a
customer’s facility.

Author(s)
David Farrell
Resource Type
Technical Paper
Event
IPC APEX 2003

Yield Prediction for Area Array Assemblies Using Monte Carlo Simulation

The advent of fine pitch area array components and the constant drive to reduce the cost of electronic products
mandate the enhancement of manufacturing systems and assembly yields. In fine pitch area array packaging,
significant cost benefits can be obtained with yield prediction at the design stage and allowing control of the
variations in the process for good assembly yields. This includes optimizing the substrate designs to compensate for
the process variations to reduce the formation of electrical opens and bridgings in the assembly. The present paper
discusses the development of a yield prediction model for area array assemblies using Monte Carlo simulation. The
simulation model was developed with the objective function of predicting the defect levels. The yield prediction
involved several critical parameters including the substrate pad dimensions,solder bump height,solder volume,
warpage and pad layout on the component. A public domain program,“Surface Evolver”,was also used in the
course of this yield modeling effort to calculate the solder joint shape. The Monte Carlo simulation based model can
be used for conducting sensitivity analysis of various design parameters and their effects on the assembly yield.

Author(s)
Vinodh Poyyapakkam,Peter Borgesen,K. Srihari
Resource Type
Technical Paper
Event
IPC APEX 2003

A Cost Effective Solution for Supporting Populated Circuit Boards during the Solder Paste Print Operation

Support tooling for circuit boards whose undersides are populated with electronic components is delicate,time
consuming to setup,and relatively expensive. This is because support pins or dedicated work holders have to avoid
applying direct and concentrated mechanical loads to electronic components located on the underside of the board.
A number of automatic pin adjustment solutions are currently available to PCB manufacturers,but these systems are
relatively expensive and some of them cannot be used without applying concentrated and potentially damaging loads
to the components. These systems are also sensitive to component placement variations. A new cost effective
method of supporting circuit boards during the solder paste print process has been developed. This study investigates
the performance of this new type of support in handling boards with components mounted on their underside as well
as unpopulated boards. This new support is in the form of a gel made of a polyurethane elastomer. The gel board
support is compared to a conventional board support solution.

Author(s)
Anand Bhosale,Daryl L. Santos,Gerald Pham-Van-Diep,John Morini,Randy Peckham
Resource Type
Technical Paper
Event
IPC APEX 2003

Study of Assembly Processes for Solder Flip Chips on FR-4 Substrates

Flip chip assembly is a key capability to enable product miniaturization. Our previous studies have investigated several flip chip
interconnection types including anisotropic conductive film or paste,and Au-Au thermosonic bonding. This project is focused
on the assembly of 0.200 and 0.250 mm pitch solder flip chip devices. Two methods of applying flux for the flip chip are
investigated: the dip fluxing method,and the jet fluxing of the substrate. The placement accuracy of a traditional SMT pick and
place system (upgraded for flip chip) is investigated and results discussed. The impact of the reflow process in air vs. nitrogen is
examined. Two underfill materials are evaluated for compatibility with the flux. Results of reliability testing (including thermal
cycling,mechanical shock and vibration) will be presented.

Author(s)
David A. Geiger,Jonas Sjoberg,Patrick Wong,Dongkai Shangguan
Resource Type
Technical Paper
Event
IPC APEX 2003

A Simpler Approach to Cost-Effective Solder Paste Testing

The increasing demand for portable electronic
products has accelerated the quest for even greater
miniaturization. At the current state of electronic
production technology,volume and weight
reductions have been achieved through the
application of SMT and Direct Attach components.
One result has been a tremendous increase in solder
paste usage. The world market for this material is
predicted to increase from US $679M in 2000 to
approximately US $2Billion by the year 2007.1
The proper performance of solder paste in forming
physical and electrical connections is vital to the
quality and reliability of SMT assemblies.
Unfortunately,most end users of solder paste have
limited knowledge and equipment for comprehensive
and in-depth evaluation of solder paste to ensure
optimum quality.
The increasing application of solder paste calls for
serious consideration its importance within the
context of quality management systems such as
TQM,ISO 9001 and QS 9001. Particularly when
process improvements are required through SPC or
other tools,the understanding of solder paste quality
issues becomes a requirement.

Author(s)
Ineke Van Tiggelen-Aarden
Resource Type
Technical Paper
Event
IPC APEX 2003