The transition from eutectic tin-lead to lead-free soldering in electronic assembly,mandatedby the RoHS legislation, has brought great pressure and challenge to solder material formulationdue to the high soldering temperature and high alloy surface tension. Moreover,the demand for halogen-free materials,which should be transparent toprocess yields,along withtheminiaturization trend in the electronic industry,is triggering arevolution in solder flux and paste formulations.The chemicalandmaterialinteractionsrelatedtosoldering andassemblyprocesses are many and varied. In general, the chemicals have to bestable during handling at mild temperaturesto warrant a process-friendlyshelf-life.Whileatpreheatandsoldering temperatures,thesolderfluxort h e pastehave to provide thermal transfer to the joint area and reactwiththemetallizationontheprintedcircuitboard(PCB) andcomponentleadstoremoveoxideandsurfacecontaminationinordertopreparethesurfaceforgood metallurgicalbonding,prevent re-oxidation with the atmosphere until the solder alloy re-solidifies,and promote wetting to form the joint.Residuescreatedbythefluxcontainmetalsalts,aswellasorganicandinorganic byproducts.A traditional formulation mainly relies on organic-based materials,rosins and carboxylic acidsto promote fluxing.Several attempts to understand the reactivity of organic acids and halogenated species have demonstrated the complexity of the chemical systems involved in fluxing mechanisms. Amine based formulations were mostly found in the old days,in the forms of ammonium orammonium halides. Here,we report a preliminary study aiming at giving some insight into the role of amines in electronic assembly applications. Our work shows that practical tests can be developed to characterize some fundamental properties of the activator packageswhich directly impact the final performance. The studyofinteractions between individual components within the systemis another key aspect of the design work.From that perspective,we intend to demonstrate that the formulator can develop robust formula based on scientific principles and rational studies rather than empirical knowledge and trial-and-error approaches.