Solder Joint Embrittlement Mechanisms,Solutions and Standards
The change to lead-free solders in electronic assemblies created a need to replace tin-lead solderable termination finishes with materials such as pure tin or soft gold,on electronic components and substrates. Gold presented a risk of solder joint embrittlement,which could reduce the joint mechanical durability. Several case studies were run,because solder joint embrittlement prevention requires a clear understanding of the materials and mechanisms of embrittlement. We confirmed two known mechanisms and verified two other ways in which gold finishes can degrade solder joints. The known mechanisms are,1) A gold layer dissolves from one side of a surface mount joint and precipitates AuSn4 compound onto the opposing termination and 2) The gold fully dissolves from a surface mount termination,but it results in an excessive gold weight percentage in the joint. The other ways are,3) A manual soldering process temperature is high enough to dissolve some nickel along with the gold and 4) A slow dissolving,hard gold surface finish incompletely dissolves during plated-through-hole soldering and solid state diffusion forms an AuSn2 compound layer. Close-up and cross-sectional images with SEM/EDS compositional information are shown for each case. A table of solder and gold volumes,which produce 3.0 and 4.0 weight percent gold,is provided. The embrittlement problems and their reliability solutions are discussed (over twenty literature references). The data suggests how to improve gold plating requirements,for solder joint embrittlement prevention,in solder assembly industry standards.