Copper Tin Intermetallic Crystals and Their Role in the Formation of Microbridges between the Leads of Hand Reworked Fine Pitch Components
Wave soldering is a mature manufacturing process that metallurgically joins component and PWB termination features by
passing them together across the flowing surface of a molten solder reservoir. During this exposure,copper from through holes,surface mount lands,and component leads,continually dissolves into the molten solder. Unless the solder in the reservoir is Regularly changed,the dissolved copper eventually reaches a point of saturation,and orthorhombic Cu6Sn5 crystals begin to precipitate out of the molten solder,causing it to become gritty and sluggish. Solder drawn from such a saturated wave solder pot can solidify into joints whose surface finish exhibits many needle like metallic protrusions. These protrusions are in fact orthorhombic Cu6Sn5 crystals. Recently,BAE Systems has determined that this same phenomenon is responsible for the formation of nearly invisible intermetallic microbridges between fine pitch surface mount component leads. They form when a solder bridge from a surface mount paste reflow operation is hand reworked with a soldering iron and copper desoldering braid. This paper documents several short circuit failures caused by this phenomenon,the investigation that identified the root cause of the problem,and the rework techniques that can be used to prevent its
occurrence.