Executive Summary
There are many issues to consider when developing a new circuit material for the PCB industry. It is a given assumption that the new material must be compatible to standard PCB fabrication processes and that by itself is a daunting task. The desired properties of new materials today are also to be robust in multiple lamination cycles,repeated lead free solder reflow cycles,multilayer capable and have consistent electrical performance.
This paper outlines a new material which meets the needs mentioned and is also halogen free,very robust to thermal cycling and is a consistent mid loss material.
Theta® circuit materials (TH) is a new material and in this study it was compared to many other materials in the industry. Since there was no known material with the same properties,a direct comparison was not available. Comparison to industry known good materials for different properties were used for this study.
Another test of thermal process stability is the eyebrow crack test. This is done on a multilayer with several layers of stacked via’s. When exposing the circuit to 288°C solder float,a circuit with good thermally robust material will typically withstand 3X cycles and the TH materials were good after 6X cycles. The pictures below shows the circuit made with the TH materials on the left,after passing 6X soldering cycles and another circuit to the right with different materials which failed after 3X cycles.
The electrical performance is also important and especially for high speed digital applications. In those applications dispersion can be important. Dispersion is how much the dielectric constant of the material will change with a change in frequency. The following graph shows dispersion curves of three materials.

With the miniaturization of components in the semiconductor industry,the need for specialized solder pastes with finer powder mesh sizes for package-on-package (PoP) assemblies has become imperative and increasingly more common. As the powder mesh size decreases (smaller diameter powder),more surface area of powder within the paste is exposed and,therefore,more susceptible to oxidation. The flux vehicle of the solder paste consequentially has more oxides to remove in order to allow for proper coalescence to form a good solder joint. The intent of this paper is to evaluate whether the decreased powder mesh size and increased oxide content of the powder in the PoP pastes affects the voiding performance of the materials,and to what degree.

Lead-free solder is more than a swap for SnPb and more than simply an alternative alloy. Five years after implementation discussion remains regarding which alloy is the best for which application. Alternative lead-free solders are available with doping of small amounts of elements to improve reliability. This study is compares Sn3,0Ag0,5Cu with low-silver Sn1,0Ag0,7Cu0,05NiGe and Sn0,7Cu0,05NiGe,a modified SnCu alloy.
A design of experiment was done to define the process window of the different alloys. Different flux preheat and solder temperatures were part of the experiment. For each alloy,the preferred parameters were defined to establish a reliable soldering process. The boards were soldered using these settings and reliability levels were tested. The test boards included different pad and barrel dimensions. This returns recommendations for designers to define the optimal pin-to-hole ratio for the different alloys.
For each alloy,the test boards were thermal cycled at -40C/+125C (30’/10”/30’) and aged at +125C for 1000 hours. The study included tensile strength measurements,intermetallic thickness growth,cross sections and visual inspection according to IPC standards.
The same alloys were used for reflow soldering. Solder paste with the same flux chemistry was used to perform reliability experiments. The presentation discusses the alloys’ performance. It also explains the benefits of adding small elements to an alloy and how to establish a compatible selection for reflow and wave alloys.

Electronic Assemblies are cleaned in order to remove contaminations that may affect yields,service life and reliability. Highly dense interconnects entrap flux residues under the Z-axis. Volatile solvents commonly used for cleaning include trichloroethylene,normal propyl bromide and a variety of other blended compounds (HFE,HFC,HCFC,etc.). Some of these solvent can have negative effects on the environment and workers. Alternative volatile solvents suitable for cleaning highly dense interconnects are needed. The purpose of this research to introduce an innovative method for cleaning electronic assemblies using a low volatile cleaning fluid followed by rinsing in an environmentally safe volatile solvent. Dual solvent cleaning provides a means for engineering cleaning fluids that match up to the soil and to be rinsed using a volatile solvent blend. This research will also report process integration between the cleaning fluids,cleaning equipment,and solvent recovery.

There are a variety of stencil approaches in which the new product process engineer can deal with the assembly of both high solder paste and low solder paste volume in an SMT assembly environment. Traditional approaches have heretofore favored aperture manipulation,multiple stencil printing and chemically or mechanically altered stencils which include a “step”. Some of these approaches present either a compromise or a non-workable option for building new products reliably and quickly. This paper presents a new approach delivering on the need for fast delivery and enough solder paste volume differential between the low solder paste and higher solder paste volume requirements. Presented will be the method and the results of an initial printing study determining amongst other things the solder paste volume delivered to the areas of different stencil height.

Jetting of liquids is becoming the standard in our industry. MYDATA has developed a unique tool to jet solder paste. This non-contact method of applying solder paste has a large number of advantages compared to standard screen printing or dispensing. The challenges of today’s production environment are not only the fact that components getting smaller but the biggest challenge is the combination of small and large components on the same board. Putting the right amount of solder paste for each component will be required to deliver the right quality. The jetting technology allows to build up the volume by single dots to achieve the right amount for each component. Special applications like pin in paste,applying paste in cavities and many more challenges of today’s requirement can be easily accommodated with this technology. Practical production challenges will be covered and a suggested solution will be provided.

The case of processing issues with Electroless Nickel/Immersion Gold (ENIG) is well documented,even as it endures as a very popular surface finish. Certainly the market says that quality ENIG has some advantages over other surface finishes. This presentation will present data surrounding the question of whether best practice process control and quality assurance are sufficient to ensure reliable solderability after multiple reflow cycles. Or is it perhaps a frequent case of bath longevity and process capability being oversold?
This presentation will also address mitigation strategies such as:
Ni bath control (fewer MTOs)
XRF control charting
The new IPC spread test solderability “W” coupon after reflow preconditioning

Moisture poses a significant threat to the reliability of microelectronic assemblies,especially for scientific research products that are designed for marine environment and can be attributed as being one of the principal causes of many early-life failures. The presence of moisture in plastic packaging alters thermal stress through alteration of thermo-mechanical properties like,change of elastic modulus,shear strength and glass transition temperatures. Moisture also induces hygroscopic stress through differential swelling,reduces interfacial adhesion strength,induces corrosion and acts as an unwanted resistance when present between the two nodes of component and result in lowering the resistance which results in faster depletion of budgeted power. In this study,an analytical model was developed and validated both by experiments and simulation to determine the ingress rate of the moisture through bi-material interface. Moisture diffusion ingress rate is calculated and validated through finite element modeling. After calculating diffusion coefficients of the two polyurethane materials,moisture ingress rate was calculated using analytical model and also simulated through finite element analysis. The diffusion coefficient was experimentally determined using absorption data (Mt/M8) by weight gain experiment as prescribe in ASTM D570 method. Once the diffusivity coefficient is known,theoretical Fickian curve is plotted with the experimental data to see if the absorption is Fickian or not. For very prolonged times,curve becomes non-fickian,therefore,diffusion coefficient is calculated by considering only the linear part of the curve. The 99% saturation approach helps to define the limit of Fickian diffusion hence eliminate error caused by non-fickian absorption. Since the Fick’s moisture diffusion equation follows the same governing differential equation as the diffusion of heat,with a change of the dependent variable,temperature,with moisture concentration and the thermal diffusivity with moisture diffusivity,commercially available heat transfer simulation software can by used to solve transient moisture diffusion problem. However,a unique problem arises in the diffusion of moisture. Since diffusion coefficient is constant for particular material,for bi-material analysis,interfacial concentration discontinuity cannot be analyzed as an interfacial discontinuity result where two materials having different saturated concentrations are joined. The results of ingress rate through FEA simulation came close to the calculated values hence validating the model.

There has been increasing interest in the development of capillary ion chromatography (IC) systems and methods for determination of ionic species. The practice of ion chromatography in capillary format offers a number of advantages. Because the eluent consumption is very low,capillary IC systems can be operated continuously and thus are always on and always ready for analysis. Capillary IC systems offer improved compatibility with applications where amount of sample is limited. Capillary IC systems provide improved performance for determination of target analyses at trace levels. The use of capillary columns can improve separation efficiency and/or speed. The operation of capillary IC systems at low flow rates improves the system compatibility with a mass spectrometer. In addition,the use of capillary separation columns opens the door for the possibility of offering new selectivity for difficult applications using new columns packed with stationary phases which are more costly and difficult to prepare.

TLPS materials are an attractive alternative to PbSn for IC power device packaging. They provide a low VOC composition,lead free die attach solution that meets the RoHS guidelines. TLPS materials also demonstrate the desired electrical and thermal reliability properties demanded by these devices. Industry changes to green compositions and cleaner assembly materials normally draw great cost increases due to change of operation. TLPS materials are managing the technical properties for conductivity and thermal drain at lower costs than the precious metal-containing materials being offered today as Pb-free die attach options for IC power device packages.