TOF SIMS Analysis for SnxOy Determination on Lead-Free HASL PCB’s
During the production of Lead-Free Hot Air Solder Leveling (LF HASL),non-wetting issues in several components were found including BGA pad. The common visual aspect of the suspicious pads was the typical yellowish and bluish color. However,during traditional Scanning Electron Microscopy/Electron Dispersive X-Ray Spectroscopy (SEM/EDX) analysis for wetting issues only a small increasing of copper was found but not related to the problem. Because of that,Time-Of-Flight Secondary Ion Mass Spectroscopy (TOF SIMS) analysis was proposed; using this technique,we could achieve better surface analysis in which we found the root cause on non-wetting just in nanometers of penetration.
With this non-common tool,the results showed something not detected before: the yellowish were zones with different thick oxide layers (about 250 nm) undetectable by SEM/EDX -four times higher than a normal oxide thickness. Consequently,solder paste flux was not able to clean that oxide thickness and joints were not formed properly. The oxide is expected to be Sn2O3 and not SnO2,the most common tin oxide. In this part,we would also conclude the activation level of solder paste flux depends on the type of oxide. With this information,an investigation was conducted to remove the oxide layer as much as possible,so a solder paste with a flux more suitable to eliminate it was implemented and a cleaning process was designed to reduce it. These actions decreased the defects. In conclusion,TOF-SIMS analysis is a tool to understand better the solderability topics in Electronics Industry.